Anionic polymerization of Z,Z-2,4hexadienedinitrile

Sivaram, S. ; Kalyanam, N. ; Bhardwaj, I. S. (1982) Anionic polymerization of Z,Z-2,4hexadienedinitrile Journal of Macromolecular Science: Part A - Chemistry, 18 (7-8). pp. 1135-1140. ISSN 1060-1325

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Official URL: http://www.tandfonline.com/doi/abs/10.1080/0022233...

Related URL: http://dx.doi.org/10.1080/00222338208066484

Abstract

Z,Z-2,4-Hexadienedinitrile, synthesized by the oxidative cleavage of o-phenylenediamine, was found to undergo anionic polymerization with n-BuLi in DMF at room temperature or below. The polymerization behavior appears to be similar to that of acrylonitrile polymerization using n-BuLi as initiator. Infrared and NMR analysis of the polymer indicate the presence of both 1,4 and 1,2 linkages, with the latter predominating.

Item Type:Article
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