On the heat of formation of [C6H4]+·

Maccoll, Allan ; Mathur, Deepak (1981) On the heat of formation of [C6H4]+· OMS(Organic Mass Spectrometry), 16 (6). pp. 261-263. ISSN 0030-493X

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Official URL: http://onlinelibrary.wiley.com/doi/10.1002/oms.121...

Related URL: http://dx.doi.org/10.1002/oms.1210160608


The appearance energy of the[C6H4]+·ion from benzonitrile has been measured, using an electron monochromator. The value observed at onset, 12.54± 0.03 eV, leads to a heat of formation of 1304± 3 kJ mol-1. Possible reasons for widely divergent values reported previously are proposed.

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