Electron capture collisions of Kr2+(3P) in H2

Mathur, D. ; Badrinathan, C. ; Rajgara, F. A. ; Raheja, U. T. (1985) Electron capture collisions of Kr2+(3P) in H2 Journal of Physics B: Atomic and Molecular Physics, 18 (24). pp. 4795-4804. ISSN 0022-3700

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Official URL: http://iopscience.iop.org/0022-3700/18/24/018

Related URL: http://dx.doi.org/10.1088/0022-3700/18/24/018


Single-electron-capture cross sections for Kr2+-H2 collisions in the 1-6 keV energy range are determined using the initial growth curve technique. Energy defect measurements reveal that the incident Kr2+ beam is purely in the ground electronic state and that the product Kr+ ions are predominantly in the 2P and 2S states. Charge transfer occurs via avoided crossings of pseudo-molecular potential energy surfaces as well as by non-crossing, Demkov-type mechanisms (1964).

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