Trimethylamine sensing properties of thorium-incorporated tin oxide

Niranjan, R. S. ; Londhe, Meghana S. ; Mandale, A. B. ; Sainkar, S. R. ; Prabhumirashi, L. S. ; Vijayamohanan, K. ; Mulla, I. S. (2002) Trimethylamine sensing properties of thorium-incorporated tin oxide Sensors and Actuators B: Chemical, 87 (3). pp. 406-413. ISSN 0925-4005

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Official URL: http://www.sciencedirect.com/science/article/pii/S...

Related URL: http://dx.doi.org/10.1016/S0925-4005(02)00288-5

Abstract

We report the trimethylamine (TMA) sensing properties of thoria-incorporated tin oxide. The tin oxide pellet having 3 wt.% of thoria exhibits a high sensitivity of 1500 towards 800 ppm of TMA compared to only 18 of pure tin oxide at a lower operating temperature of 225 °C. The incorporation of thorium in tin oxide enhances the sensitivity towards TMA with improved selectivity. The effect of surface coverage, morphology and oxidation state on the sensitivity has been studied using techniques like scanning electron microscopy (SEM), X-ray diffraction (XRD) and X-ray photoelectron spectroscopy (XPS). The correlation between thoria incorporation in the tin oxide at different sintering temperatures and the improvement in the selectivity and sensitivity towards TMA is discussed.

Item Type:Article
Source:Copyright of this article belongs to Elsevier Science.
Keywords:TMA; Tin Oxide; Thorium Oxide; Sensor
ID Code:68901
Deposited On:08 Nov 2011 04:36
Last Modified:08 Nov 2011 04:36

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