Kinetics of electrode reactions occurring on porous iron electrodes in alkaline media

Vijayamohanan, K. ; Shukla, A. K. ; Sathyanarayana, S. (1990) Kinetics of electrode reactions occurring on porous iron electrodes in alkaline media Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, 295 (1-2). pp. 59-70. ISSN 0022-0728

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Official URL: http://www.sciencedirect.com/science/article/pii/0...

Related URL: http://dx.doi.org/10.1016/0022-0728(90)85005-P

Abstract

The kinetics of iron and hydrogen electrode reactions occurring on porous alkaline iron electrodes have been studied with the help of steady state and transient galvanostatic polarisation. Galvanostatic transients of porous iron electrodes in the linear polarisation regime have been analysed quantitatively, accounting for the charge-transfer and ohmic components of iron electrode reactions as well as the charge-transfer component of the hydrogen evolution reaction. These data, as also the volume of hydrogen evolved during these experiments, substantiate the catalytic effects of ferrous sulphide additives.

Item Type:Article
Source:Copyright of this article belongs to Elsevier Science.
ID Code:68851
Deposited On:07 Nov 2011 05:01
Last Modified:17 Jul 2012 08:36

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