Kinetics of aquation of Pentaammine(substituted salicylato)cobalt(III) complexes by ferric ion

Dash, Anadi C. ; Nanda, Rabindra K. ; Patnaik, Himansu K. (1977) Kinetics of aquation of Pentaammine(substituted salicylato)cobalt(III) complexes by ferric ion Transition Metal Chemistry, 2 (1). pp. 183-185. ISSN 0340-4285

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Official URL: http://www.springerlink.com/content/x35483068168r2...

Related URL: http://dx.doi.org/10.1007/BF01402717

Abstract

The aquation of pentaammine (substituted salicylato) cobalt(III) complexes [(NH3)5CoO2CC6H3(X)OH]2+, X = 5-SO3, 5-Br, 5-NO2, and 3-NO2 in the presence of ferric ion was studied spectrophotometrically in the 65° - 80° range. Ferric ion catalyses the aquation of the substratesvia formation of a reactive binuclear species.

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