Kinetics and mechanism of the formation of (1,8)bis(2-hydroxybenzamido)3,6-diazaoctaneiron(III) and its reactions with thiocyanate, azide, acetate, sulfur(IV) and ascorbic acid in solution, and the synthesis and characterization of a novel oxo bridged diiron(III) complex. The role of phenol-amide-amine coordination

Nayak, Suprava ; Dash, Anadi C. (2006) Kinetics and mechanism of the formation of (1,8)bis(2-hydroxybenzamido)3,6-diazaoctaneiron(III) and its reactions with thiocyanate, azide, acetate, sulfur(IV) and ascorbic acid in solution, and the synthesis and characterization of a novel oxo bridged diiron(III) complex. The role of phenol-amide-amine coordination Transition Metal Chemistry, 31 (6). pp. 813-828. ISSN 0340-4285

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Official URL: http://www.springerlink.com/content/t4116l37qx10nt...

Related URL: http://dx.doi.org/10.1007/s11243-006-0079-0

Abstract

We investigate the impact of the 766.3 Ty KamLAND spectrum data on the determination of the solar neutrino oscillation parameters. We show that the observed spectrum distortion in the KamLAND experiment firmly establishes Δm221 to lie in the low-LMA solution region. The high-LMA solution is excluded at more than 4σ by the global solar neutrino and KamLAND spectrum data. The maximal solar neutrino mixing is ruled out at 6σ level. The 3σ allowed region in the Δm221 − sin2θ12 plane is found to be remarkably stable with respect to leaving out the data from one of the solar neutrino experiments from the global analysis. We perform a three flavor neutrino oscillation analysis of the global solar neutrino and KamLAND spectrum data as well. The 3σ upper limit on sin2θ13 is found to be sin2θ13<0.055. We derive predictions for the CC to NC event rate ratio and day-night (D-N) asymmetry in the CC event rate, measured in the SNO experiment, and for the suppression of the event rate in the BOREXINO and LowNu experiments. Prospective high precision measurements of the solar neutrino oscillation parameters are also discussed.

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Deposited On:03 Nov 2011 07:39
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