Electron paramagnetic resonance study of Mn2+-doped iron, cobalt, and nickel perchlorate hexahydrates

Dayal, R. ; Ramachandra Rao, D. ; Venkateswarlu, Putcha (1979) Electron paramagnetic resonance study of Mn2+-doped iron, cobalt, and nickel perchlorate hexahydrates Journal of Magnetic Resonance - Series A, 36 (1). pp. 99-111. ISSN 1064-1858

Full text not available from this repository.

Official URL: http://www.sciencedirect.com/science/article/pii/0...

Related URL: http://dx.doi.org/10.1016/0022-2364(79)90219-1

Abstract

Mn2+-doped Fe(CIO4)2·6H2O, Co(ClO4)2·6H2O, and Ni(ClO4)2·6H2O have been studied by EPR from room temperature to liquid nitrogen temperature. Mn2+ replaces the metal ions at sites of trigonal symmetry. The EPR lines are broad and the D parameters are small; thus, there is considerable overlap in the spectra. The spectra are nearly axially symmetric. The temperature variation study shows phase transitions at 237 ± 5, 154.5 ± 6.5, and 223 ± 5 K in iron, cobalt, and nickel perchlorate hexahydrates, respectively.

Item Type:Article
Source:Copyright of this article belongs to Elsevier Science.
ID Code:68637
Deposited On:02 Nov 2011 10:56
Last Modified:02 Nov 2011 10:56

Repository Staff Only: item control page