Absorption spectrum of manganese acetate tetrahydrate

Mehra, Anjani ; Venkateswarlu, Putcha (1968) Absorption spectrum of manganese acetate tetrahydrate The Journal of Chemical Physics, 48 (10). pp. 4381-4383. ISSN 0021-9606

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Official URL: http://jcp.aip.org/resource/1/jcpsa6/v48/i10/p4381...

Related URL: http://dx.doi.org/10.1063/1.1668004


The absorption spectrum of Mn(CH3COO)2·4H2O has been studied at 300° and 77°K. The band positions have been fitted in terms of the parameters B, C, Dq, and α , and the values of the parameters obtained for the 300°K spectrum are 820, 3000, 760, and 76 cm−1, respectively. There are two types of Mn2+ sites in the crystal and the expected features of the fine-structure lines arising from the two types of ions in the 77°K spectrum are discussed.

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