Spin-orbit coupling parameter for Mn2+ in RbMnF3

Mehra, Anjani ; Venkateswarlu, Putcha (1967) Spin-orbit coupling parameter for Mn2+ in RbMnF3 Physical Review Letters, 19 (4). pp. 145-146. ISSN 0031-9007

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Official URL: http://prl.aps.org/abstract/PRL/v19/i4/p145_1

Related URL: http://dx.doi.org/10.1103/PhysRevLett.19.145


Fine structure observed in the 6A1g(S)→4T2g(D) band in the absorption spectrum of RbMnF3 at 77°K has been assigned to the spin-orbit splitting of the 4T2g(D) level, and the analysis yields a value of 320 ± 10 cm-1 for the parameter ξ3d.

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