Optical absorption studies of Co (CH3COO)2·4H2O

Narayana, P. A. ; Mehra, A. ; Venkateswarlu, Putcha (1968) Optical absorption studies of Co (CH3COO)2·4H2O Canadian Journal of Physics, 46 (5). pp. 325-329. ISSN 0008-4204

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Official URL: http://www.nrcresearchpress.com/doi/abs/10.1139/p6...

Related URL: http://dx.doi.org/10.1139/p68-048


The absorption spectrum of Co(CH3COO)2·4H2O has been studied at room temperature and at 78 °; K. The cubic field approximation with Dq = 960 cm−1, B = 850 cm−1, and C = 4.5B is found to give a good fit to the observed band positions. The spin-forbidden transitions from the quartet ground state to upper doublet levels have been observed, and their intensities and positions are discussed.

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