Absorption spectrum of Mn2+ in KCl

Mehra, Anjani ; Venkateswarlu, Putcha (1966) Absorption spectrum of Mn2+ in KCl The Journal of Chemical Physics, 45 (9). 3381_1-3381_3. ISSN 0021-9606

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Official URL: http://jcp.aip.org/resource/1/jcpsa6/v45/i9/p3381_...

Related URL: http://dx.doi.org/10.1063/1.1728118


The absorption spectrum of an Mn2+-doped KCl crystal has been measured at room temperature. The observed bands are assigned as transitions from the 6A1(S) ground state to various excited quartet levels of a Mn2+ ion in a cubic crystalline field. The observed band energies are fitted with four parameters B, C, Dq, and a and the values obtained for the parameters in cm−1 are B=760, C=2955, Dq=590, and α =76.

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