Urey-Bradley force constants, mean amplitudes of vibration, shrinkage effect and Coriolis constants in IF5 and IOF5

Venkateswarlu, K. ; Purushothaman, C. (1968) Urey-Bradley force constants, mean amplitudes of vibration, shrinkage effect and Coriolis constants in IF5 and IOF5 acta physica Academiae Scientiarum Hungaricae, 25 (2). pp. 133-140. ISSN 0001-6705

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Official URL: http://www.springerlink.com/content/t221574u2g67h3...

Related URL: http://dx.doi.org/10.1007/BF03157117

Abstract

Force constants of the molecules IF5 and IOF5 have been calculated using the Urey - Bradley force field. The theory of mean square amplitude matrices is applied to these cases and the parallel and perpendicular mean square amplitudes at 300° K are determined. The perpendicular amplitudes are employed for calculating theBastiansen-Morino shrinkage effects. The Coriolis constants of these molecules are also evaluated.

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