Choudary, B. M. ; Pal, Ujjwal ; Lakshmi Kantam, M. ; Ranganath, K. V. S. ; Sreedhar, B. (2006) Asymmetric epoxidation of olefins by manganese(III) complexes stabilised on nanocrystalline magnesium oxide Advanced Synthesis & Catalysis, 348 (9). pp. 1038-1042. ISSN 1615-4150
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Official URL: http://onlinelibrary.wiley.com/doi/10.1002/adsc.20...
Related URL: http://dx.doi.org/10.1002/adsc.200505428
Abstract
The asymmetric epoxidation of unfunctionalised olefins to epoxides is realised by using manganese(III) complexes stabilised on nanocrystalline magnesium oxide in the presence (1R,2R)-(-)-diaminocyclohexane as a chiral ligand in good yields and up to 91% enantiomeric excess.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to John Wiley and Sons, Inc. |
| Keywords: | Asymmetric Epoxidation; Heterogeneous Catalysis; Magnesium Oxide; Manganese Acetylacetonate; Nanocrystalline Materials |
| ID Code: | 6816 |
| Deposited On: | 26 Oct 2010 05:28 |
| Last Modified: | 28 May 2011 08:13 |
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