The first example of activation of molecular oxygen by nickel in Ni-Al hydrotalcite: a novel protocol for the selective oxidation of alcohols

Choudary, B. M. ; Lakshmi Kantam, M. ; Rahman, Ateeq ; Venkat Reddy, Ch. ; Koteswara Rao, K. (2001) The first example of activation of molecular oxygen by nickel in Ni-Al hydrotalcite: a novel protocol for the selective oxidation of alcohols Angewandte Chemie International Edition, 40 (4). pp. 763-766. ISSN 1433-7851

Full text not available from this repository.

Official URL: http://onlinelibrary.wiley.com/doi/10.1002/1521-37...

Related URL: http://dx.doi.org/10.1002/1521-3773(20010216)40:4<763::AID-ANIE7630>3.0.CO;2-T

Abstract

NiO in association with aluminum oxide has been identified by temperature-programmed reduction as the active species in the Ni–Al hydrotalcite catalyst that oxidizes α-ketols as well as benzylic and allylic alcohols to their corresponding carbonyl compounds in oxygen in quantitative yields under mild reaction conditions.

Item Type:Article
Source:Copyright of this article belongs to John Wiley and Sons.
Keywords:Alcohols; Hydrotalcites; Oxidation; Oxygen; Reduction
ID Code:6813
Deposited On:26 Oct 2010 05:28
Last Modified:28 May 2011 09:12

Repository Staff Only: item control page