Decarbonylative metalation of diformylphenol Schiff bases: new osmium and ruthenium organ ometallics incorporating the iminium-phenolato zwitterionic motif

Ghosh, Prasanta ; Bag, Nilkamal ; Chakravorty, Animesh (1996) Decarbonylative metalation of diformylphenol Schiff bases: new osmium and ruthenium organ ometallics incorporating the iminium-phenolato zwitterionic motif Organometallics, 15 (13). pp. 3042-3047. ISSN 0276-7333

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Official URL: http://pubs.acs.org/doi/abs/10.1021/om960018b

Related URL: http://dx.doi.org/10.1021/om960018b

Abstract

The reaction of Schiff bases of 2,6-diformyl-4-methylphenol with M(PPh3)3X2 in ethanol has afforded carbonylhalo[4-methyl-6-(N-R-iminiomethyl)phenolato-C2,O]bis(triphenylphosphine)metal(II) compounds, MII(RL)(PPh3)2(CO)X (M = Os, X = Br; M = Ru, X = Cl; R = alkyl, aryl). The process is believed to proceed via oxidative addition of the aldehydic C(O)-H bond to the metal followed by CO extrusion and reductive proton elimination. The X-ray structure of Os(EtL)(PPh3)2(CO)Br·CH2Cl2 has revealed the presence of the distorted octahedral OsC2P2BrO coordination sphere. In the four-membered, Os(C,O) chelate ring, the metal atom is bonded to the carbon site to which an aldehyde group was attached in the parent ligand. The presence of the iminium-phenolato zwitterionic motif is consistent with the N···O length as well as with IR and 1H NMR spectra. Bond parameters of the osmium and ruthenium systems are compared. Significant dπ-pπ back-bonding with the metalated aromatic ring occurs in the case of osmium. The complexes display a quasi-reversible one-electron cyclic voltammetric couple (E1/2 = 0.50-0.70 V), but the oxidized congeners are too unstable to be isolated. Upon reaction of M(RL)(PPh3)2(CO)X with carboxylates, the latter gets chelated, the M-O(phenolato) linkage is cleaved, and the iminium-phenolato function tautomerizes to the imine-phenol function.

Item Type:Article
Source:Copyright of this article belongs to American Chemical Society.
ID Code:6763
Deposited On:22 Oct 2010 06:37
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