Determination of cation oxidation states in the spinel ZnMnFeO4 by X-ray spectroscopy

Mande, C. ; Kulkarni, D. K. ; Chetal, A. R. (1969) Determination of cation oxidation states in the spinel ZnMnFeO4 by X-ray spectroscopy Journal of Physics D: Applied Physics, 2 (4). pp. 635-636. ISSN 0022-3727

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Official URL: http://iopscience.iop.org/0022-3727/2/4/126

Related URL: http://dx.doi.org/10.1088/0022-3727/2/4/126

Abstract

The K absorption edges of zinc, manganese and iron have been recorded photographically in the spinel ZnMnFeO4, using a bent-crystal x-ray spectrograph. The positions of these edges have been compared with those in some bivalent and trivalent compounds. This comparison shows that the valence states of zinc, manganese and iron in this spinel are 2, 3 and 3 respectively.

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