Linear soluble polybenzyls

Som, Abhijit ; Ramakrishnan, S. (2003) Linear soluble polybenzyls Journal of Polymer Science Part A: Polymer Chemistry, 41 (15). pp. 2345-2353. ISSN 0887-624X

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Linear soluble polybenzyls, although deceptively simple in structure, have been strangely elusive. We report for the first time the synthesis of perfectly linear soluble polybenzyls by the polycondensation of 1,2,4,5-tetrasubstituted benzenes with formaldehyde using CHCl3/trifluoroacetic acid (TFA) as the medium, wherein TFA served both as an acidic catalyst as well as a cosolvent. The number-average molecular weights (Mn's) of the polymers, as determined by gel permeation chromatography, varied from about 1000 to 37,000, depending on the nature of the substituent on the benzene ring; Mn was highest when all four substituents were alkoxy groups and was lowest when they were all alkyl groups. This correlated well with susceptibility of the aromatic ring toward electrophilic aromatic substitution, which is the underlying polymerization mechanism. Differential scanning calorimetry of the polymers showed that most of the samples were amorphous with glass-transition temperatures ranging from about -80° to +80 °C, whereas a few that were either symmetrically substituted or possessed a long alkyl substituent were partially crystalline. Preliminary studies suggested that the methylene unit linking the phenyl rings in these polybenzyls could be readily oxidized to generate conjugated polymers that may be perceived as carbon analogues of polyaniline-poly(arylmethine)s.

Item Type:Article
Source:Copyright of this article belongs to John Wiley and Sons.
Keywords:Conjugated Polymers; Friedel-crafts Polycondensation; Linear Poly(benzyl)s
ID Code:67239
Deposited On:29 Oct 2011 12:04
Last Modified:29 Oct 2011 12:04

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