Catalytic asymmetric dihydroxylation of aliphatic olefins with reusable resin-osmium tetroxide

Choudary, Boyapati M. ; Jyothi, Karangula ; Madhi, Sateesh ; Kantam, M. Lakshmi (2003) Catalytic asymmetric dihydroxylation of aliphatic olefins with reusable resin-osmium tetroxide Advanced Synthesis & Catalysis, 345 (11). pp. 1190-1192. ISSN 1615-4150

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Official URL: http://onlinelibrary.wiley.com/doi/10.1002/adsc.20...

Related URL: http://dx.doi.org/10.1002/adsc.200303114

Abstract

Asymmetric dihydroxylation of aliphatic olefins to chiral diols with good yields and ees by a heterogeneous Resin-OsO4 catalyst using ferricyanide as cooxidant is disclosed for the first time. The catalyst was recovered quantitatively by simple filtration and reused for several times without significant loss of activity.

Item Type:Article
Source:Copyright of this article belongs to John Wiley and Sons, Inc.
Keywords:Aliphatic Olefins; Asymmetric Dihydroxylation; Chiral Diols; Immobilization; Supported Catalysts; Resin-osmium Tetroxide
ID Code:6679
Deposited On:22 Oct 2010 05:30
Last Modified:28 May 2011 08:59

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