A trifunctional catalyst for the synthesis of chiral diols

Choudary, Boyapati M. ; Chowdari, Naidu S. ; Madhi, Sateesh ; Kantam, Mannepalli L. (2001) A trifunctional catalyst for the synthesis of chiral diols Angewandte Chemie International Edition, 40 (24). pp. 4619-4623. ISSN 1433-7851

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Official URL: http://www3.interscience.wiley.com/journal/8901080...

Related URL: http://dx.doi.org/10.1002/1521-3773(20011217)


A transition metal based biomimic approach is used to realize multistep reactions, composed of multicomponent systems, in a single-pot synthesis of chiral diols mediated by a trifunctional (Pd, Os, W) catalyst anchored to a single matrix (see scheme; LDH=layered double hydroxide, (DHQD)2PHAL=1,4-bis(9-O-dihydroquinidinyl)phthalazine, NMM=N-methylmorpholine).

Item Type:Article
Source:Copyright of this article belongs to John Wiley and Sons, Inc.
Keywords:Asymmetric Synthesis; Heterogeneous Catalysis; Immobilization; Oxidation; Transition Metals
ID Code:6667
Deposited On:22 Oct 2010 05:25
Last Modified:28 May 2011 09:10

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