Choudary, Boyapati M. ; Madhi, Sateesh ; Kantam, Mannepalli L. ; Sreedhar, Bojja ; Iwasawa, Yasuhiro (2004) Synthesis of surface organopalladium intermediates in coupling reactions: the mechanistic insight Journal of the American Chemical Society, 126 (8). pp. 2292-2293. ISSN 0002-7863
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Official URL: http://pubs.acs.org/doi/abs/10.1021/ja038270f
Related URL: http://dx.doi.org/10.1021/ja038270f
Abstract
The design and synthesis of surface transient organometallic intermediates on nanopalladium supported on layered double hydroxides is conceived and developed for the first time. The formation of only one STO intermediate in all the Heck-, Suzuki-, Sonogashira-, and Stille-type coupling reactions during their reaction sequences and the excellent isolated yields of each of the coupling products from the corresponding organometallic complexes not only validate the mechanism but also demonstrate the evolution of the single-site heterogeneous catalyst.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to American Chemical Society. |
| ID Code: | 6664 |
| Deposited On: | 22 Oct 2010 05:26 |
| Last Modified: | 28 May 2011 08:57 |
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