A study in crystal engineering: solid-state photodimerization of chloro- and methyl-coumarins

Gnanaguru, K. ; Murthy, G. S. ; Venkatesan, K. ; Ramamurthy, V. (1984) A study in crystal engineering: solid-state photodimerization of chloro- and methyl-coumarins Chemical Physics Letters, 109 (3). pp. 255-258. ISSN 0009-2614

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Official URL: http://www.sciencedirect.com/science/article/pii/0...

Related URL: http://dx.doi.org/10.1016/0009-2614(84)85730-9 |

Abstract

Use of chloro and methyl substitution in crystal engineering and their interchangeability in terms of mode of packing have been examined in a series of substituted coumarins. Photoreactivity in the solid state lists been correlated with the crystallograhic structures of these coumarins. The packing of chloro-substituted aromatic compounds has been investigated by analysing the arrangement of 132 compounds. Results substantiate the use of the chloro group as a steering agent and show that the chloro and methyl groups are not always interchangeable.

Item Type:Article
Source:Copyright of this article belongs to Elsevier Science.
ID Code:66616
Deposited On:27 Oct 2011 04:08
Last Modified:27 Oct 2011 04:08

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