Madhavaiah, C. ; Parvez, Masood ; Verma, Sandeep (2004) Catalytic transformations with copper-metalated diglycine conjugates Bioorganic & Medicinal Chemistry, 12 (22). pp. 5973-5982. ISSN 0968-0896
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Official URL: http://www.sciencedirect.com/science/article/pii/S...
Related URL: http://dx.doi.org/10.1016/j.bmc.2004.08.018
Abstract
A series of copper-metalated, water-soluble bis-diglycine conjugates were synthesized and characterized through spectroscopic methods. These conjugates were evaluated for the cleavage of phosphodiester substrates, supercoiled plasmid relaxation in the presence of co-oxidants, and for the oxidation of a diphenolic substrate, 2,6-dimethoxyphenol. Appreciable rate enhancements were observed for these reactions and the oxidative nucleolytic cleavage activity and phenol oxidative coupling was presumably manifested via formation of reactive oxygen species.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| Keywords: | Diglycine; Copper; Catalysis; Plasmid; Oxidation |
| ID Code: | 66221 |
| Deposited On: | 21 Oct 2011 09:44 |
| Last Modified: | 21 Oct 2011 09:44 |
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