Purohit, Chandra Shekhar ; Parvez, Masood ; Verma, Sandeep (2007) Kinetic characterization of a bioinspired, heterogeneously active macromolecular catalyst for phenol oxidation and coupling reactions Applied Catalysis A: General, 316 (1). pp. 100-106. ISSN 0926-860X
Full text not available from this repository.
Official URL: http://www.sciencedirect.com/science/article/pii/S...
Related URL: http://dx.doi.org/10.1016/j.apcata.2006.09.024
Abstract
We have synthesized and characterized a novel copper metalated polymeric matrix of modified nucleobase cytosine that catalyses oxidation of phenolic substrates. This metalated polymer is insoluble in common organic solvents, thus catalysis is heterogeneous in nature so that the material can be reused. The molecular structure of the monomer and the metalated monomer, a Michaelis-Menten kinetic analysis of oxidative transformations using different phenolic substrates and mechanistic investigations are presented in this paper.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| Keywords: | Cytosine; Copper; Heterogeneous Catalysis; Phenol Oxidation |
| ID Code: | 66216 |
| Deposited On: | 21 Oct 2011 09:59 |
| Last Modified: | 21 Oct 2011 09:59 |
Repository Staff Only: item control page
