Madhavaiah, C. ; Srivatsan, S. G. ; Verma, Sandeep (2001) Ruthenium-metallated adenine nucleobase polymers as novel reagents for catalytic cleavage of phosphate esters Catalysis Communications, 2 (3-4). pp. 95-99. ISSN 1566-7367
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Official URL: http://www.sciencedirect.com/science/article/pii/S...
Related URL: http://dx.doi.org/10.1016/S1566-7367(01)00014-0
Abstract
A ruthenium-impregnated resin has been used for the catalytic cleavage of model phosphate ester (P-ester) substrates and highly efficient hydrolytic rate enhancements were obtained. Remarkably, million-fold rate acceleration was observed for a phosphodiester substrate. A thorough Michaelis-Menten kinetic analysis of this resin-catalyzed hydrolytic reaction, using three different phosphate monoester and diester substrates, is presented in this communication.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| ID Code: | 66185 |
| Deposited On: | 21 Oct 2011 09:42 |
| Last Modified: | 21 Oct 2011 09:42 |
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