Srinivas, O. ; Muktha, B. ; Radhika, S. ; Guru Row, T. N. ; Jayaramana, N. (2004) Crystal structure of N-(benzyloxycarbonyl)aminoethyl-2,3,4,6-tetra-O-benzoyl-α-D-mannopyranoside: stabilization of the crystal lattice by a tandem network of N-H···O, C-H···O, and C-H···Π interactions Carbohydrate Research, 339 (6). pp. 1087-1092. ISSN 0008-6215
Full text not available from this repository.
Official URL: http://www.sciencedirect.com/science/article/pii/S...
Related URL: http://dx.doi.org/10.1016/j.carres.2004.02.009
Abstract
Single crystal X-ray analysis of an aminoethyl mannopyranoside, namely, N-(benzyloxycarbonyl)aminoethyl-2,3,4,6-tetra-O-benzoyl-α -D-mannopyranoside (1), shows that the compound crystallizes in the monoclinic space group P21, with two molecules in the unit cell. The mannopyranoside unit adopts a distorted 4C1 conformation. An analysis of the intermolecular interactions reveals a tandem network of N-H···O, C-H···O, and C-H···Π interactions responsible for stabilizing the crystal lattice. The single crystal X-ray structure of N-(benzyloxycarbonyl)aminoethyl-2,3,4,6-tetra-O-benzoyl-α -D-mannopyranoside is determined. An analysis of the packing motif reveals that a tandem network of N-H···O, C-H···O, and C-H···Π interactions emerges to stabilize the molecular packing in the solid state.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| Keywords: | Carbohydrate; Crystal Structure; Hydrogen Bonding; Mannopyranoside; Weak Interactions |
| ID Code: | 66001 |
| Deposited On: | 20 Oct 2011 07:10 |
| Last Modified: | 11 Jul 2012 04:12 |
Repository Staff Only: item control page
