Growing molecular crystals on inorganic crystals: polar structure induced by noncentrosymmetric templates

Jaya Prakash, M. ; Raghavaiah, Pallepogu ; Krishna, Y. S. R. ; Radhakrishnan, T. P. (2008) Growing molecular crystals on inorganic crystals: polar structure induced by noncentrosymmetric templates Angewandte Chemie International Edition, 47 (21). pp. 3969-39702. ISSN 1433-7851

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Official URL: http://onlinelibrary.wiley.com/doi/10.1002/anie.20...

Related URL: http://dx.doi.org/10.1002/anie.200704031

Abstract

Like promotes like: The templating effect of inorganic crystals is exploited to promote the growth of the polar structure of a molecular crystal of a dipolar zinc(II) complex (see picture). It is likely that the polar nature of the noncentrosymmetric template crystal lattice, and its associated electrostatic field, facilitates the oriented assembly of the dipolar molecules.

Item Type:Article
Source:Copyright of this article belongs to John Wiley and Sons.
Keywords:Crystal Growth; Polar Crystals; Polymorphism; Second Harmonic Generation; Template Synthesis
ID Code:65930
Deposited On:19 Oct 2011 14:25
Last Modified:19 Oct 2011 14:25

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