Differential reactivity pattern of hybrid o-quinodimethane precursors: strategic expansion to annulated benzocycloalkanes via rongalite

Kotha, Sambasivarao ; Khedkar, Priti (2009) Differential reactivity pattern of hybrid o-quinodimethane precursors: strategic expansion to annulated benzocycloalkanes via rongalite Journal of Organic Chemistry, 74 (15). pp. 5667-5670. ISSN 0022-3263

Full text not available from this repository.

Official URL: http://pubs.acs.org/doi/abs/10.1021/jo900658z?

Related URL: http://dx.doi.org/10.1021/jo900658z

Abstract

A hybrid benzocyclobutene (BCB) molecular frames embedding sultine or sulfone moiety has been synthesized via utilization of rongalite. The selective Diels-Alder reaction has been realized at sultine or sulfone terminus in the hybrid BCB system to prepare functionalized BCB molecular frames. The methodology has been generalized for assembling various benzocycloalkanes containing a sultine unit and the strategy has been expanded to generate various annulated benzocycloalkanes.

Item Type:Article
Source:Copyright of this article belongs to American Chemical Society.
ID Code:65212
Deposited On:15 Oct 2011 11:46
Last Modified:15 Oct 2011 11:46

Repository Staff Only: item control page