Mohapatra, Himansu ; Umapathy, S. (2010) Time-resolved resonance raman studies on proton-induced electron-transfer reaction from triplet excited state of 2-methoxynaphthalene to decafluorobenzophenone The Journal of Physical Chemistry A, 114 (47). pp. 12447-12451. ISSN 1089-5639
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Official URL: http://pubs.acs.org/doi/abs/10.1021/jp109821r
Related URL: http://dx.doi.org/10.1021/jp109821r
Abstract
In this paper, time-resolved resonance Raman (TR3) spectra of intermediates generated by proton-induced electron-transfer reaction between triplet 2-methoxynaphthalene (3ROMe) and decafluorobenzophenone (DFBP) are presented. The TR3 vibrational spectra and structure of 2- methoxynaphthalene cation radical (ROMe•+) have been analyzed by density functional theory (DFT) calculation. It is observed that the structure of naphthalene ring of ROMe•+ deviates from the structure of cation radical of naphthalene.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to American Chemical Society. |
| ID Code: | 65002 |
| Deposited On: | 15 Oct 2011 12:40 |
| Last Modified: | 15 Oct 2011 12:40 |
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