The AC resistivity of borate glasses containing antimony and arsenic oxide

Chakravorty, D. ; Kishore Kumar, L. G. (1982) The AC resistivity of borate glasses containing antimony and arsenic oxide Journal of Physics D: Applied Physics, 15 (6). pp. 1089-1095. ISSN 0022-3727

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Official URL: http://iopscience.iop.org/0022-3727/15/6/018

Related URL: http://dx.doi.org/10.1088/0022-3727/15/6/018

Abstract

The AC resistivities of some borate glasses containing either antimony oxide or arsenic oxide have been measured over a temperature range 125K to 400K. A sharp minimum in the resistivity values for all the compositions is observed around 280K. This behaviour is explained on the basis of a change in the ratio of A5+/A3+ (where A=Sb or As) as a function of temperature. The AC resistivity for temperatures below 280K is found to obey a ω−s law with 0.5 < s < 0.9. A bipolaronic conduction model is used to calculate the density of charged centres in these glasses.

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