Yadav, J. S. ; Satyanarayana Ready, P. ; Joshi, Bhalchandra V. (1988) A convenient reduction of alkylated tosylmethyl isocyanides : applications for the synthesis of natural products Tetrahedron, 44 (23). pp. 7243-7254. ISSN 0040-4020
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Official URL: http://www.sciencedirect.com/science/article/pii/S...
Related URL: http://dx.doi.org/10.1016/S0040-4020(01)86095-6
Abstract
A convenient and simple method for the reduction of mono- and diatkylated tosylmethyl isocyanides with lithium in liquid ammonia to corresponding hydrocarbons is described. The utility of this methodology adopted in the synthesis of tricos-9Z-ene. (7g), a. sex pheromone of common house fly, (-)-1S.5R, 7S-exo-brevicomin (17), an antipode of sex pheromone of Western pine beetle and (4S,5S)-5-hydroxy-4-decanolide (L-factor, 19), a proposed autoregulator for leukaemomycin biosynthesis.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| ID Code: | 64526 |
| Deposited On: | 08 Oct 2011 12:28 |
| Last Modified: | 08 Oct 2011 12:28 |
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