Rama Rao, A. V. ; Yadav, J. S. ; Srinivas Rao, C. ; Chandrasekhar, S. (1990) Radical cyclization in stereospecific introduction of chirality at 'off template site' of 1,2-O-isopropylidene-α-D-xylo-hexofuranose Journal of the Chemical Society, Perkin Transactions 1 (4). pp. 1211-1213. ISSN 0300-922X
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Official URL: http://pubs.rsc.org/en/Content/ArticleLanding/1990...
Related URL: http://dx.doi.org/10.1039/P19900001211
Abstract
Bromoacetals derived from 5,6-dideoxy-1,2-O-isopropylidene-α-D-xylo-hex-5-ynofuranose (9) undergo facile free radical cyclization leading to the formation of olefinic acetals which are chemially manipulated to introduce either of the chiralities at C-5 of α-D-hexofuranose.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Royal Society of Chemistry. |
| ID Code: | 64525 |
| Deposited On: | 08 Oct 2011 12:28 |
| Last Modified: | 05 Jul 2012 11:43 |
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