Reddy, Pattubala A. N. ; Datta, Riya ; Chakravarty, Akhil R. (2000) Synthesis, X-ray structure and catalytic properties of a copper(II) Schiff base complex modeling the activity of the CuB site of dopamine β-hydroxylase Inorganica Chimica Acta, 3 (6). pp. 322-324. ISSN 0020-1693
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Official URL: http://linkinghub.elsevier.com/retrieve/pii/S13877...
Related URL: http://dx.doi.org/10.1016/S1387-7003(00)00083-6
Abstract
The copper(II) complex [Cu(salgly)(bpy)]·4H2O (1), where salgly is a tridentate glycinatosalicylaldimine Schiff base ligand, is prepared and structurally characterized. The complex is found to be catalytically active in the oxidation of ascorbic acid by dioxygen and the process is also effective in the presence of benzylamine giving benzaldehyde as a product, thus modeling the activity of the CuB site of dopamine β-hydroxylase.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| Keywords: | Copper(II) complexes; Schiff-base complexes; Dopamine ß-hydroxylase model; Catalytic properties; Ascorbate oxidation |
| ID Code: | 6449 |
| Deposited On: | 20 Oct 2010 10:21 |
| Last Modified: | 27 May 2011 05:13 |
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