Mandal, Sisir K. ; Chakravarty, Akhil R. (1991) Syntheses, X-ray structure and properties of (5-cyclopentadienyl)ruthenium(II) complexes of pyridyl-2-hydrazone ligands Polyhedron, 10 (20-21). pp. 2483-2486. ISSN 0277-5387
Full text not available from this repository.
Official URL: http://linkinghub.elsevier.com/retrieve/pii/S02775...
Related URL: http://dx.doi.org/10.1016/S0277-5387(00)86213-0
Abstract
Complexes of the formulae [(-Cp)Ru(PPh3)(2-PPH)]Cl and [(Cp)Ru(PPh3) (py)(1-PPH)]Cl were prepared by reacting pyridyl-2-phenylhydrazone [PPH, C5H4N-2-CH=NNHPh] with (-Cp)Ru(PPh3)2Cl and (-Cp)Ru(PPh3)(py)Cl, respectively. In these complexes the PPH ligand displays bidentate chelating and unidentate modes of bonding. The molecular structure of [(-Cp)Ru(PPh3)(2-PPH)](ClO4)·CH2Cl2 was determined by X-ray crystallography. In this complex the metal is bonded to the N-pyridyl and N-imine atoms of the chelating ligand. 1H NMR spectral data suggests that PPH is bonded to ruthenium through the pyridine moiety of the PPH ligand in [(η-Cp)Ru(PPh3)(py)(η1-PPH)]Cl.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| ID Code: | 6435 |
| Deposited On: | 20 Oct 2010 10:24 |
| Last Modified: | 27 May 2011 05:26 |
Repository Staff Only: item control page
