Neelakandan, Prakash P. ; Hariharan, Mahesh ; Ramaiah, Danaboyina (2005) Synthesis of a novel cyclic donor-acceptor conjugate for selective recognition of ATP Organic Letters, 7 (26). pp. 5765-5768. ISSN 1523-7060
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Official URL: http://pubs.acs.org/doi/abs/10.1021/ol052246k
Related URL: http://dx.doi.org/10.1021/ol052246k
Abstract
Novel cyclophane 1 was synthesized, and its interactions with phosphate, adenosine, AMP, ADP, and ATP have been investigated. With addition of ATP, significant decrease in absorbance of 1 was observed, whereas other guest molecules showed negligible effect. The complex between 1 and ATP was confirmed through cyclic voltammetry and 1H NMR. The uniqueness of the system is that it complexes selectively with ATP in a cavity and involves synergistic effects of both electrostatic and π-π stacking interactions.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to American Chemical Society. |
| ID Code: | 63606 |
| Deposited On: | 29 Sep 2011 04:00 |
| Last Modified: | 29 Sep 2011 04:00 |
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