Addition of carbon nucleophiles to aldehyde tosylhydrazones of aromatic and heteroaromatic-compounds: total synthesis of piperine and its analogs

Chandrasekhar, S. ; Venkat Reddy, M. ; Srinivasa Reddy, K. ; Ramarao, C. (2000) Addition of carbon nucleophiles to aldehyde tosylhydrazones of aromatic and heteroaromatic-compounds: total synthesis of piperine and its analogs Tetrahedron Letters, 41 (15). pp. 2667-2670. ISSN 0040-4039

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Official URL: http://www.sciencedirect.com/science/article/pii/S...

Related URL: http://dx.doi.org/10.1016/S0040-4039(00)00219-7

Abstract

Addition of carbon nucleophiles to aldehyde tosylhydrazones of aromatic and heteroaromatic compounds is reported. New observations have been made wherein alkylative reduction is observed in some cases whereas alkylative fragmentation is noticed in others. These findings are exploited in the synthesis of the useful alkaloid piperine and its analogs.

Item Type:Article
Source:Copyright of this article belongs to Elsevier Science.
Keywords:Toluene-p-sulphonylhydrazine; Piperine; Anti-feedant; Insecticide
ID Code:63509
Deposited On:29 Sep 2011 04:15
Last Modified:29 Sep 2011 04:15

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