Chandrasekhar, S. ; Raji Reddy, Ch. ; Jagadeeshwar Rao, R. (2001) Facile and selective cleavage of allyl ethers, amines and esters using polymethylhydrosiloxane-ZnCl2/Pd(PPh3)4 Tetrahedron, 57 (16). pp. 3435-3438. ISSN 0040-4020
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Official URL: http://www.sciencedirect.com/science/article/pii/S...
Related URL: http://dx.doi.org/10.1016/S0040-4020(01)00187-9
Abstract
Allyl deprotection to liberate free hydroxy, amino and acid groups from the corresponding allyl ethers, amines and esters is achieved under mild conditions. The reagent combination employed for this transformation is polymethylhydrosiloxane (PMHS), ZnCl2 and Pd(PPh3)4.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| Keywords: | Allylic Protecting Groups; Polymethylhydrosiloxane; Palladium Catalysis; Zinc Chloride |
| ID Code: | 63501 |
| Deposited On: | 28 Sep 2011 19:11 |
| Last Modified: | 29 Sep 2011 04:16 |
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