Unprecedented direct conversion of N-N and N=N bonds to N-(tert-butyloxy)-carbamates

Chandrasekhar, S. ; Raji Reddy, Ch. ; Jagadeeshwar Rao, R. (2001) Unprecedented direct conversion of N-N and N=N bonds to N-(tert-butyloxy)-carbamates Synlett, 2001 (10). pp. 1561-1562. ISSN 0936-5214

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Official URL: https://www.thieme-connect.com/ejournals/abstract/...

Related URL: http://dx.doi.org/10.1055/s-2001-17439

Abstract

For the first time a one step direct conversion of aromatic hydrazines and azo compounds to N-(tert-butoxycarbonyl) amines is achieved via reductive cleavage of N-N and N=N bonds using the inexpensive and safe hydride source polymethylhydrosiloxane (PMHS) and di-tert-butyl dicarbonate [(Boc)2O] in the presence of a catalytic amount of 10% Pd-C.

Item Type:Article
Source:Copyright of this article belongs to Thieme Medical Publishers.
Keywords:Polymethylhydrosiloxane; Hydrazines; Azo Compounds; Tert-butyl Carbamates; One-pot Reaction
ID Code:63498
Deposited On:29 Sep 2011 04:16
Last Modified:29 Sep 2011 04:16

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