Chandrasekhar, S. ; Raji Reddy, Ch. ; Jagadeeshwar Rao, R. ; Madhusudana Rao, J. (2002) Efficient and chemoselective deoxygenation of amine N-oxides using polymethylhydrosiloxane Synlett, 2002 (2). 0349-0351. ISSN 0936-5214
Full text not available from this repository.
Official URL: https://www.thieme-connect.com/ejournals/abstract/...
Related URL: http://dx.doi.org/10.1055/s-2002-19751
Abstract
Deoxygenation of aromatic and aliphatic amine N-oxides to the corresponding amines is achieved under mild conditions. The reagent combination employed for this transformation is polymethylhydrosiloxane (PMHS) in the presence of either tetrakis (triphenylphosphine) palladium (0) [Pd(PPh3)4], titanium (IV) isopropoxide [Ti(i-PrO)4] or palladium on carbon (Pd/C).
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Thieme Medical Publishers. |
| Keywords: | Amine N-oxides; Polymethylhydrosiloxane; Palladium Catalysis; Titanium(IV)Isopropoxide |
| ID Code: | 63495 |
| Deposited On: | 29 Sep 2011 04:16 |
| Last Modified: | 29 Sep 2011 04:16 |
Repository Staff Only: item control page
