Shivaiah, Vaddypally ; Das, Samar K. (2005) Supramolecular assembly based on a heteropolyanion: synthesis and crystal structure of Na3(H2O)6[Al(OH)6Mo6O18]·2H2O Journal of Chemical Sciences, 117 (3). pp. 227-233. ISSN 0253-4134
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Official URL: http://www.ias.ac.in/chemsci/Pdf-May2005/227.pdf
Related URL: http://dx.doi.org/10.1007/BF02709291
Abstract
Synthesis and structural characterization of a polyoxometalate compound Na3(H2O)6 [Al(OH)6Mo6O18]·2H2O (1) have been described. Compound1 exhibits three-dimensional network structure in the solid state, which is assembled by Anderson-type heteropolyanions, [Al(OH)6Mo6O18]n3n- , as building blocks sharing sodium cations.1 possesses "sinuous" channels occupied by supramolecular water dimers as guests. Anderson anions, sodium-coordinated water and crystal water are additionally involved in an intricate hydrogen-bonding network in the crystal of 1.
| Item Type: | Article |
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| Source: | Copyright of this article belongs to Indian Academy of Sciences. |
| Keywords: | Anderson-type Heteropolyanions; Sodium Cation as Linkers; Three-dimensional Network Structure; Guest Supramolecular Water Dimers; Hydrogen-bonding Interactions |
| ID Code: | 63461 |
| Deposited On: | 29 Sep 2011 04:25 |
| Last Modified: | 18 May 2016 12:14 |
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