A novel polyoxometalate chain formed from heteropolyanion building blocks and rare earth metal ion linkers: [La(H2O)7Al(OH)6Mo6O18]n·4nH2O

Shivaiah, Vaddypally ; Narasimha Reddy, Puram V. ; Cronin, Leroy ; Das, Samar K. (2002) A novel polyoxometalate chain formed from heteropolyanion building blocks and rare earth metal ion linkers: [La(H2O)7Al(OH)6Mo6O18]n·4nH2O Journal of the Chemical Society Dalton Transactions (20). pp. 3781-3782. ISSN 1472-7773

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Official URL: http://pubs.rsc.org/en/content/articlelanding/2002...

Related URL: http://dx.doi.org/10.1039/B207149E

Abstract

The structure of the complex [La(H2O)7Al(OH)6Mo6O18]n·4nH2O is the first example of a 1D extended chain in which an Anderson type heteropolyanion is linked by rare earth metal ions in zig-zag chains that arrange "head to tail" in the structure; furthermore the chains are themselves linked into an extensive three-dimensional hydrogen bonded network.

Item Type:Article
Source:Copyright of this article belongs to Royal Society of Chemistry.
ID Code:63455
Deposited On:29 Sep 2011 04:22
Last Modified:18 May 2016 12:14

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