Madhu, V. ; Das, Samar K. (2005) Supramolecular Π-Π assembly of a neutral [Cu(salen)] complex via the templating effect of an ionic inorganic complex Na2[Cu(mnt)2] forming a framework type material having well-defined channels Inorganic Chemistry Communications, 8 (12). pp. 1097-1100. ISSN 1387-7003
Full text not available from this repository.
Official URL: http://www.sciencedirect.com/science/article/pii/S...
Related URL: http://dx.doi.org/10.1016/j.inoche.2005.08.016
Abstract
A classical ionic inorganic complex Na2[Cu(mnt)2] (mnt2- = maleonitriledithiolate = 1,2-dicyanoethylenedithiolate), that acts as a template in assembling neutral [Cu(salen)] (salen = bis(salicylidene)ethylenediamine) complexes forming a framework type arrangement, is accommodated in the channel formed in the crystal structure of a new type of host-guest compound [Cu(salen)]4 · Na2[Cu(mnt)2] (1). The non-covalent supramolecular interactions among [Cu(salen)] complexes and between [Cu(salen)] and [Cu(mnt)2]2- complexes in the crystal lattice of 1 result in weak antiferromagnetic coupling.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| Keywords: | Copper-schiff-base Complex; Π-Π-assembly; Framework Type Material; Supramolecular Chemistry; Templating Effect; Dithiolate |
| ID Code: | 63415 |
| Deposited On: | 29 Sep 2011 04:28 |
| Last Modified: | 29 Sep 2011 04:28 |
Repository Staff Only: item control page
