Pradeep, Chullikkattil P. ; Zacharias, Panthapally S. ; Das, Samar K. (2008) Identification of ONO···ONO interactions among inorganic coordination complex molecules in the crystal lattice of a chiral Mn(IV) compound Inorganic Chemistry Communications, 11 (1). pp. 89-93. ISSN 1387-7003
Full text not available from this repository.
Official URL: http://www.sciencedirect.com/science/article/pii/S...
Related URL: http://dx.doi.org/10.1016/j.inoche.2007.10.019
Abstract
The chiral Schiff base ligand H2L on reaction with Mn(CH3COO)2 · 4H2O in methanol gave a yellow precipitate, which on recrystallization from dimethylformamide (DMF) solvent solvent gave dark-brown needle shaped crystals of a chiral Mn(IV) compound [MnL2] · DMF (1). Crystal structure analysis of compound 1 revealed an interesting O···O non-covalent interaction between -NO2 groups present on adjacent [MnIVL2] complex units which leads to the formation of chainlike arrangement in the crystal lattice of the relevant complex.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| Keywords: | Chiral Mn(IV) Complex; Crystal Structure; Nitro-nitro Interaction; Supramolecular Chemistry |
| ID Code: | 63413 |
| Deposited On: | 29 Sep 2011 04:30 |
| Last Modified: | 29 Sep 2011 04:30 |
Repository Staff Only: item control page
