Chirality of a Strandberg-type heteropolyanion [S2Mo5O23]4-

Shivaiaha, Vaddypally ; Arumuganathana, T. ; Das, Samar K. (2004) Chirality of a Strandberg-type heteropolyanion [S2Mo5O23]4- Inorganic Chemistry Communications, 7 (3). pp. 367-369. ISSN 1387-7003

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The heteropolyanion [S2Mo5O23]4- having C2 symmetry is dissymmetric and hence expected to be chiral. The heteropoly-compound [NMe4]4[S2Mo5O23] exhibits its both enantiomers in DMSO solution by a Pfeiffer effect when l- and d-arabinose are used as environment substances.

Item Type:Article
Source:Copyright of this article belongs to Elsevier Science.
Keywords:Strandberg Type Heteropolyanion; Recemic Mixtures; Circular Dichroism Studies; Pfeiffer Effect
ID Code:63412
Deposited On:29 Sep 2011 04:24
Last Modified:29 Sep 2011 04:24

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