Shivaiah, Vaddypally ; Das, Samar K. (2005) Fivefold coordination of a CuII-aqua ion: a supramolecular sandwich consisting of two crown ether molecules and a trigonal-bipyramidal [Cu(H2O)5]2+ complex Angewandte Chemie International Edition, 45 (2). pp. 245-248. ISSN 1433-7851
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Official URL: http://onlinelibrary.wiley.com/doi/10.1002/anie.20...
Related URL: http://dx.doi.org/10.1002/anie.200503096
Abstract
Copper crowned: A trigonal-bipyramidal [Cu(H2O)5]2+ ion, which is inserted between two crown ether molecules ([18]crown-6) to form a unique supramolecular sandwich, [Cu(H2O)5([18]crown-6)2]2+ (see picture), has been characterized unambiguously by single-crystal X-ray diffraction. Isopolyanions, [Mo6O19]2-, facilitate the formation of this new structure.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to John Wiley and Sons. |
| Keywords: | Copper; Crown Compounds; Polyanions; Sandwich Complexes; Supramolecular Chemistry |
| ID Code: | 63411 |
| Deposited On: | 29 Sep 2011 04:29 |
| Last Modified: | 29 Sep 2011 04:29 |
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