Müller, Achim ; Krickemeyer, Erich ; Bögge, Hartmut ; Schmidtmann, Marc ; Beugholt, Christian ; Das, Samar K. ; Peters, Frank (1999) Giant ring-shaped building blocks linked to form a layered cluster network with nanosized channels: [Mo124VIMo28VO429(μ3-O)28H14(H2O)66.5]16- Chemistry - A European Journal, 5 (5). pp. 1496-1502. ISSN 0947-6539
Full text not available from this repository.
Official URL: http://onlinelibrary.wiley.com/doi/10.1002/(SICI)1...
Related URL: http://dx.doi.org/10.1002/(SICI)1521-3765(19990503)5:5<1496::AID-CHEM1496>3.0.CO;2-D
Abstract
A novel type of electron-rich (basic!) nanosized channels can be built up by linking giant ring-shaped building blocks, which occur in the layered compound of composition [Mo124VIMo28VO429(μ3-O)28H14(H2O)66.5]16- (see figure). The corresponding sodium salt is obtained by reduction of an acidified aqueous molybdate solution under special reaction conditions.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to John Wiley and Sons. |
| Keywords: | Inorganic Rings; Layered Compounds; Mixed-valent Compounds; Molybdenum Blue; Supramolecular Chemistry |
| ID Code: | 63410 |
| Deposited On: | 29 Sep 2011 04:21 |
| Last Modified: | 29 Sep 2011 04:21 |
Repository Staff Only: item control page
