Müller, Achim ; Das, Samar K. ; Kögerler, Paul ; Bögge, Hartmut ; Schmidtmann, Marc ; Trautwein, Alfred X. ; Schünemann, Volker ; Krickemeyer, Erich ; Preetz, Wilhelm (2000) A new type of supramolecular compound: molybdenum-oxide-based composites consisting of magnetic nanocapsules with encapsulated keggin-ion electron reservoirs cross-linked to a two-dimensional network Angewandte Chemie International Edition, 39 (19). pp. 3413-3417. ISSN 1433-7851
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Official URL: http://onlinelibrary.wiley.com/doi/10.1002/1521-37...
Related URL: http://dx.doi.org/10.1002/1521-3773(20001002)39:19<3413::AID-ANIE3413>3.0.CO;2-Q
Abstract
Nanosized metal-oxide-based composites-novel supramolecular entities-have been assembled and even cross-linked under one-pot conditions. The supramolecular entity (see picture) consists of a paramagnetic icosahedral capsule of the type {MoVI72FeIII30} as a host which encloses a potential electron-reservoir noncovalently bonded guest, the reduced Keggin cluster [H2PMo12O40]3-.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to John Wiley and Sons. |
| Keywords: | Composites; Magnetic Properties; Materials; Polyoxometalates; Supramolecular Chemistry |
| ID Code: | 63406 |
| Deposited On: | 29 Sep 2011 04:22 |
| Last Modified: | 29 Sep 2011 04:22 |
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