Pd/CaCO3 in liquid poly(ethylene glycol) (PEG): an easy and efficient recycle system for partial reduction of alkynes to cis-olefins under a hydrogen atmosphere

Chandrasekhar, S. ; Narsihmulu, Ch. ; Chandrashekar, G. ; Shyamsunder, T. (2004) Pd/CaCO3 in liquid poly(ethylene glycol) (PEG): an easy and efficient recycle system for partial reduction of alkynes to cis-olefins under a hydrogen atmosphere Tetrahedron Letters, 45 (11). pp. 2421-2423. ISSN 0040-4039

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Official URL: http://www.sciencedirect.com/science/article/pii/S...

Related URL: http://dx.doi.org/10.1016/j.tetlet.2004.01.097

Abstract

Lindlar's catalyst (Pd/CaCO3) in PEG (400) has been found to be the most reusable reaction medium for selective reduction of alkynes to cis-olefins. The catalyst and PEG were recycled five times without loss of activity.

Item Type:Article
Source:Copyright of this article belongs to Elsevier Science.
Keywords:Hydrogenation; Lindlar's Catalyst; PEG; Recycling
ID Code:63253
Deposited On:28 Sep 2011 03:51
Last Modified:28 Sep 2011 03:51

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