Chandrasekhar, Srivari ; Srinivasa Reddy, Marepally ; Jagadeesh, Bharatam ; Prabhakar, Anabathula ; Ramana Rao, Mallem H. V. ; Jagannadh, Bulusu (2004) Formation of a stable 14-Helix in short oligomers of Furanoid cis-β-sugar-amino acid Journal of the American Chemical Society, 126 (42). pp. 13586-13587. ISSN 0002-7863
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Official URL: http://pubs.acs.org/doi/abs/10.1021/ja0467667
Related URL: http://dx.doi.org/10.1021/ja0467667
Abstract
Oligomers of a new class of sugar amino acids (SAA) using a xylofuranoic acid has been shown to generate a robust 14-helix. The design involved the use of xylofuranose with a cis arrangement between the amine and carboxyl groups to promote the adoption of a 14-helix instead of a mixed 12/10-helix observed in a sugar oligomer using a ribofuranoic acid and β-Ala. The observation of a stable right-handed 14-helix in a cis-SAA is unprecedented.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to American Chemical Society. |
| ID Code: | 63246 |
| Deposited On: | 28 Sep 2011 03:52 |
| Last Modified: | 28 Sep 2011 03:52 |
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