Yadav, J. S. ; Reddy, B. V. S. ; Srinivasa Reddy, K. ; Chandraiah, L. ; Sunitha, V. (2004) Bi(OTf)3 as novel and efficient catalyst for the stereoselective synthesis of C-pseudoglycals Synthesis, 2004 (15). pp. 2523-2526. ISSN 0039-7881
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Official URL: https://www.thieme-connect.com/ejournals/abstract/...
Related URL: http://dx.doi.org/10.1055/s-2004-831187
Abstract
D-Glycals undergo smoothly allylic rearrangement with allyltrimethylsilane and trimethylsilyl cyanide in the presence of catalytic amount of bismuth triflate to afford the corresponding 2,3-unsaturated allyl glycosides and glycosyl cyanides in excellent yields with high α-selectivity.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Thieme Medical Publishers. |
| Keywords: | Bismuth Reagents; Glycals; Pseudoglycals; C-glycosides |
| ID Code: | 63227 |
| Deposited On: | 28 Sep 2011 03:23 |
| Last Modified: | 28 Sep 2011 03:23 |
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